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How is the Stability of a coordination compound in solution decided?

& How is dissociation constant of a complex defined !????

Chemistry CBSE +2

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  • 8 years ago
    Favourite answer

    It can be defined in two ways. One can write the reaction "forward" resulting in a formation constant, Kf, or "backwards" resulting in an instability constant.

    Cu2+ + 4NH3 ===> Cu(NH3)4(2+)

    Kf = [Cu(NH4)(2+)]/[Cu2+][NH3]^4

    Cu(NH3)4(2+) ===> Cu2+ + 4NH3

    Kinst = [Cu2+][NH3]^4/[Cu2+][NH3]^4

    So long as the equilibrium constant is defined and you are consistent, either way should be good.

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